Protective adhesive film product

ABSTRACT

A protective film product for a portable electronic device includes a protective film, one or more adhesive layers formed on a surface of the protective film, a backing layer disposed on one of the adhesive layers, and a cap sheet disposed on an opposite surface of the protective film. Micro air pockets are formed in gaps between a surface of the cap sheet and the protective film.

RELATED APPLICATIONS

This application claims priority to U.S. application Ser. No. 13/044,275, filed Mar. 9, 2011, which claims domestic benefit of each of: U.S. Provisional Application No. 61/313,363, filed on Mar. 12, 2010; U.S. Provisional Application No. 61/316,185, filed on Mar. 22, 2010; U.S. Provisional Application No. 61/359,690, filed on Jun. 29, 2010; and U.S. Provisional Application No. 61/440,708, filed on Feb. 8, 2011. Each of these references is incorporated herein by reference thereto.

BACKGROUND

The present invention relates generally to methods of applying protective films to electronic device surfaces and to devices comprising protective films.

Protective films are used to cover and protect a variety of materials and devices from, for example, scratches or dents that may be imparted during transport or use of the device. Protective films may be used to protect, for example, the surface of digital electronic device components during manufacture, or may be adhered to a completed device to protect it from damage during normal day-to-day use. A variety of protective films are known, each having properties that may be advantageous for some uses and disadvantageous for other uses. One form of protective film used in the art is coated on one side with a layer of a dry pressure-sensitive adhesive that has sufficient tack to form a secure contact with the device while permitting slight repositioning of the film after adherence. Protective films are often transparent, and may permit the use of touch-sensitive features of the electronic device through the film.

Typically, when a dry protective film, particularly a protective film having an adhesive layer, is applied to a surface, air is easily trapped between a device surface and the film during application, causing the appearance of bubbles. Bubbles are undesirable for aesthetic reasons but also because their presence over an optical screen distorts images on a screen viewed by a device user. Prior methods of eliminating trapped air bubbles beneath protective films utilize an aqueous solution or other solvent to temporarily reduce adherence between a film and a device, permitting trapped air to be forced out by mechanical pressure. Known methods, for example, include spraying a protective film (or device surface) with water or another liquid, applying the wet film to the device surface to be protected (or applying the film to the wet device surface), and using pressure (e.g., with a squeegee) to smooth the film and force out any trapped air bubbles. In doing so, the water or other liquid is also forced out from between the film and the device surface, and collects at an edge of the film.

Thus, prior methods required introduction of a liquid to the outer surface of a device, requiring a user to take additional steps to remove liquid after a film is applied to a device. A significant disadvantage to using a wet solution to apply a protective film is potential introduction of liquid into an electronic device, for example, through the apertures for the speaker or head set jack. In some cases, liquid entering an interior housing of a device may cause a device to fail. For this reason, device manufacturers commonly include moisture sensitive indicators within their devices to help diagnose device failure. In some cases, a manufacturer will void a device's warranty where inspection of a device and its moisture indicators show exposure to moisture.

Another drawback of many protective films is the high visibility of fingerprints, smudges or other marks on the film, resulting, for example, from handling of a device. In particular, visibility of fingerprints or other marks on films covering electronic device bodies or display screens is aesthetically and functionally undesirable. A visible residue over a display screen, for example, may distort the transmission of light from the screen resulting in distortion of an image viewed on the screen. Matte surface treatments have been used to address this problem, but the application of typical matte surfaces over an optical screen reduces optical transmission.

SUMMARY

According to a first disclosed aspect, a protective film product for use on a touchscreen of a mobile telephone may include a protective film, one or more adhesive layers, a removable backing layer, and a removable cap sheet. The protective film may have a proximal end, a distal end and two opposing sides. The proximal end, distal end and two opposing sides together form a perimeter of the protective film, and the perimeter surrounds a planar portion of the protective film that includes a first major surface and a second major surface opposite the first major surface. The first major surface is separated from the second major surface by a thickness. The protective film has a structure configured to preserve touch sensitivity and clarity of the touchscreen of the mobile telephone.

The one or more adhesive layers may be disposed on the first major surface of the protective film, and have planar dimensions substantially coextensive with first major surface of the protective film. The removable backing layer may have a planar surface in contact with an outermost adhesive layer of the one or more adhesive layers. The backing layer may prevent contact of the one or more adhesive layers by other objects prior to installation of the protective film onto a surface of the mobile telephone, and the backing layer may have planar dimensions substantially coextensive with the first major surface of the protective film. The removable cap sheet may be disposed on the second major surface of the protective film. Micro air pockets may be formed in gaps between a surface of the cap sheet and the second major surface of the protective film.

According to another aspect of the disclosure, a protective film product for protecting at least a portion of a mobile telephone may include a protective film an adhesive layer, a removable backing layer, and a removable cap sheet having properties as follows. The protective film may have a first major surface and a second major surface opposite the first major surface, and the first major surface and the second major surface may be defined by a perimeter. The protective film may be air permeable to permit diffusion of gases. The adhesive layer may be disposed on the first major surface of the protective film. The removable backing layer may be disposed in contact with the adhesive layer to bar contact with the adhesive layer prior to removal of the backing layer during installation of the protective film onto a surface portion of the mobile telephone. The removable cap sheet may be disposed on the second major surface of the protective film. Micro air pockets may be formed in gaps between a surface of the cap sheet and the second major surface of the protective film.

In yet another aspect of the disclosure, a protective film product for use with a portable electronic device may include a protective film, an adhesive layer, a removable backing layer and a removable cap sheet respectively having properties as follows. The protective film may have a first major surface and a second major surface opposite the first major surface. The adhesive layer may be disposed on the first major surface of the protective film, and may include an adhesive that provides tack sufficient to securely adhere the protective film to a surface of the portable electronic device without the necessity of a liquid during installation of the protective film. The adhesive may also allow one or more of positioning and repositioning during the installation of the protective film. The removable backing layer may be disposed over the adhesive layer to protect the adhesive layer from contact by other objects prior to removal of the removable backing layer during installation of the protective film onto a surface of the portable electronic device. The removable cap sheet may be formed from a rigid material and may be disposed on the second major surface of the protective film. Micro air pockets may be formed in gaps between a surface of the cap sheet and the second major surface of the protective film.

Another implementation of a protective film product for a portable electronic device may include a protective film, an adhesive layer, and a removable cap sheet. The protective film may have a first major surface and a second major surface opposite the first major surface. The adhesive layer may be disposed on the first major surface of the protective film, and the removable cap sheet may be disposed on the second major surface of the protective film. Micro air pockets may be formed in gaps between a surface of the cap sheet and the second major surface of the protective film.

In addition, any of the above-described embodiments may further include one or more openings formed in the protective film for alignment with and access to an input port, an output port, a connection, a jack, and/or a button of portable electronic device (e.g., mobile telephone).

The disclosed embodiments may further include a micro-matte layer or surface structure coated on, or structurally formed as, at least part of a surface of the protective film. In some embodiments the protective film product may also include a first tab and a second tab respectively extending outward at opposite first and second edges of the protective film product. The tabs may be sized to form a grab handle to allow a user to position the protective film during its installation onto a surface of the portable electronic device (e.g., mobile telephone). The tabs may be removably divided from the protective film product by respective first and second sets of perforations.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 illustrates an exemplary adhesive film and a step for applying an adhesive film to an electronic device.

FIG. 2 illustrates an exemplary additional step for applying an adhesive film to an electronic device.

FIG. 3 illustrates an exemplary additional step for applying an adhesive film to an electronic device.

FIG. 4 illustrates an exemplary additional step for applying an adhesive film to an electronic device.

FIG. 5 illustrates an exemplary step for applying a protective adhesive film that includes a cap sheet layer to an electronic device.

FIG. 6 an exemplary additional step for applying a protective adhesive film that includes a cap sheet layer to an electronic device.

FIG. 7 illustrates an exemplary additional step for applying a protective adhesive film that includes a cap sheet layer to an electronic device.

FIG. 8 illustrates an exemplary additional step for applying a protective adhesive film that includes a cap sheet layer to an electronic device.

DETAILED DESCRIPTION

As used in the description below and in the appended claims, the singular forms “a,” “an,” and “the” include plural references unless the context clearly dictates otherwise. Unless defined otherwise, all technical and scientific terms used in this document have the same meanings as commonly understood by one of ordinary skill in the art. As used in this document, the term “comprising” means “including, but not limited to.” As used herein, the term “about” when referring to a value, means plus or minus 10% of the value.

This disclosure is not limited to the particular systems, devices and methods described, as these may vary. Also, the terminology used in this document is only for the purpose of describing particular versions or embodiments, and it is not intended to limit the scope.

Devices and methods are disclosed that avoid the need for an aqueous solution or other liquid in applying a protective adhesive film to an electronic device and removing trapped air bubbles. As described herein, a protective film comprising an adhesive layer (e.g., a pressure-sensitive adhesive layer) may be adhered to a device surface without the use of an aqueous solution to remove trapped aft bubbles. Instead, trapped air bubbles are removed by applying pressure across the film surface to mechanically eliminate large (e.g., greater than 2-3 mm in diameter) air bubbles, while permitting smaller aft bubbles to be eliminated over time. The adhesive film may be disposed on a first major surface of the protective adhesive film. As used in the document, the term “major surface” refers to a planar surface of a sheet or layer of a film. In general, a sheet will have two opposing major surfaces.

In some embodiments, a protective film may comprise a polyurethane sheet, e.g., a polycaprolactone-based aliphatic thermoplastic urethane sheet. A first major surface of a polyurethane sheet may be coated with one or more layers of a pressure-sensitive adhesive, such as a copolymer comprising an acrylate polymer and a silicone macromer. In some embodiments, the protective film is a polycaprolactone-based aliphatic thermoplastic urethane and comprises an adhesive layer consisting essentially of a copolymer of an acrylate polymer and silicone macromer side chains. A micro-matte surface structure may be formed on at least a second major surface of the sheet, as described herein. In another embodiment, a protective film may comprise a polyurethane sheet, e.g., a polycaprolactone-based aliphatic thermoplastic urethane sheet. The sheet may be coated on one side with a micro-matte layer, as described herein.

The protective adhesive film may comprise a polyurethane sheet, e.g., an aliphatic polyester urethane-based sheet, e.g., a polycaprolactone based aliphatic thermoplastic urethane sheet, coated on all or part of a first major surface (or “backed”) with an adhesive layer. In some embodiments, the adhesive layer is a pressure-sensitive adhesive layer. The pressure-sensitive adhesive layer (or coating) may be a copolymer comprising an acrylate polymer and a silicone macromer. In some embodiments, an adhesive layer thickness may be about 10 to about 100 microns, about 12 to about 75 microns, about 25 to about 38 microns, about 30 microns, or about 35 microns. The pressure-sensitive adhesive layer (or coating) may comprise an acrylate-silicone copolymer based pressure-sensitive adhesive. The adhesive layer may comprise additional components, e.g., a tackifier or plasticizer, and may be a self-healing adhesive. The adhesive layer may be formed without the use of a cross-linker or photo-initiator. The adhesive layer may be prepared using a thermal cure process. In some embodiments, the adhesive layer is made of an adhesive that does not immediately firmly secure the film to a device and thus allows for slight repositionability of the film after placement on the device. For example, the adhesive layer may include an amount of silicone to permit repositionability. In some embodiments, unpolymerized silicone, tackifier, or other low molecular weight components are included in the adhesive layer and migrate into the polyurethane sheet and modify its characteristics. A polyurethane sheet comprising an adhesive layer may be made more flexible or more impact resistant by the interaction with one or more such components from an adhesive.

In some embodiments, the adhesive layer comprises a polyacrylate-based pressure-sensitive adhesive layer, having silicone macromer side chain modifications of one or more acrylate ester groups. In some embodiments, the adhesive layer may be prepared from or comprise acrylic acid, methacrylic acid, esters of acrylic acid comprising 4 to 21 carbon atoms, esters of methacrylic acid comprising 5 to 21 carbon atoms, acrylamide, substituted acrylamides such as N,N-dimethyl acrylamide, styrene, substituted styrenes such as vinyl toluene, acrylonitrile, methacrylonitrile, N-vinyl pyrrolidone, N-vinyl caprolactam, vinylidene chloride, vinyl esters of carboxylic acids, 2-(2-ethoxyethoxy)ethyl acrylate, 2-ethylhexyl acrylate, butyl acrylate, hydroxyethyl acrylate, hydroxypropyl acrylate, 2-carboxyethyl acrylate, ethoxyethyl acrylate, perfluorooctyl acrylate, isooctyl acrylate, divinylbenzene, vinylbenzyl chloride, vinyl acetate, glycidyl methacylate, hydroethyl acetate, hydroxypropyl acetate, glacial acrylic acid, methyl acrylate, ethyl acrylate, butyl acrylate, iso butyl acrylate or other acrylates, or combinations thereof. In some embodiments, the pressure-sensitive adhesive comprises acrylate and silicone in other polymer configurations as known in the art. Suitable pressure-sensitive adhesives may be manufactured by 3M Company of St. Paul, Minn. or other manufacturing companies.

The protective film may have a thickness from about 75 microns up to about 400 microns. For example, the protective adhesive films used may have thicknesses including about 75 microns, about 100 microns, about 150 microns, about 175 microns, about 200 microns, about 250 microns, about 300 microns, or about 350 microns. Different thicknesses may be used for different parts of a device. For example, an electronic device may use a 150 micron film for the device's optical screen and a 300 micron film for the device's body. Such films may provide scratch resistance, impact resistance, or both, and may provide higher impact resistance to the parts of the device that are most likely to need it, while preserving the sensitivity and/or clarity of portions of the device that are less likely to require impact resistance.

The protective adhesive film to be adhered to a device optical screen may have a shore hardness of between about 85 A and 99 A, or between about 50 D and 7 D to provide a strong film with a flat surface with minimal or no surface distortion (e.g., “orange peel”). In some embodiments, the shore hardness of the protective adhesive film is about 60 D or about 93 A. The protective adhesive film may allow for proper optical transmission and may provide a substantially smooth surface so that it best mirrors the glass surface on the device. In addition to providing an aesthetic benefit, this allows for minimal or no reduction in sensitivity and/or connectivity for touch screens.

The device body films may have a variety of surface types, including anti-glare, glossy, or matte, and may be optically transparent, transparent with a matte texture, translucent or opaque. The film may comprise UV absorbers. The films may be colored or uncolored. In some embodiments, the protective adhesive film may comprise a surface having a micro-matte structure. Surface treatments may vary over a single device, i.e., a film covering an optical screen may have an anti-glare surface while film covering a device body may have a matte surface. A portion of a protective film to be adhered to the body of a device (portions not including the optical screen), the optical screen, or both may have a matte and/or a micro-matte finish or layer which may eliminate or reduce fingerprints and adds additional “grip” to the device. Suitable protective films may be manufactured by Argotec Inc. of Greenfield, Mass., or other similar manufacturing companies. In some embodiments, the adhesive coating or layer may be protected by a removable backing (e.g., prior to adhering the protective film to a device) before the protective adhesive film is adhered to a device surface.

A micro-matte surface structure is one that has a matte finish with an average roughness, Ra, between about 0.08 μm and about 0.22 μm, or about 0.17 μm, or about 0.135 μm. In some embodiments, a micro-matte surface structure has an average maximum height, Rz, between about 0.50 μm and about 1.20 μm, or about 1.11 μm, or about 1.23 μm. A micro-matte surface structure may have an average depth, Rmax, between about 1.30 μm and about 1.50 μm, or about 1.40 μm.

In some embodiments, a micro-matte protective film is prepared by extrusion of a urethane resin onto a micro-matte textured casting sheet which, in some embodiments, may be a PET multi-layer film. The urethane resin forms a film that, when removed from the casting sheet, retains a micro-matte surface texture on one side (e.g., a second major surface of the protective film) that mirrors the texture of the casting sheet. Thus, a film may be prepared by a single casting of urethane, rather than by addition of a micro-matte layer to a smooth urethane film. Alternatively, a micro-matte protective film may be prepared as a co-extrusion of at least two layers. Accordingly, a micro-matte protective film may be prepared using multiple resins of varying hardness such that its micro-matte structure may be harder and/or more durable as may be required for specific applications. Alternatively, a micro-matte layer may be formed on a polyurethane sheet, for example, by extruding a resin onto a urethane film and contacting the resin with a micro-matte casting sheet to form a micro-matte surface texture. The micro-matte protective film may comprise a pressure-sensitive adhesive layer or layers, which may be the same or similar to the pressure-sensitive adhesive layer or layers described above. In some embodiments, the micro-matte textured casting sheet is the same or different than the cap sheet described herein. The micro-matte structure may cover all or part of a second major surface of a protective film.

In some embodiments, a polyurethane sheet coated with a pressure-sensitive adhesive (e.g., to create a protective adhesive film) may be cut into predetermined shapes designed to fit particular portions of digital electronic devices including, but not limited to, mobile telephones, personal digital assistants, eReaders, computer notebooks, netbooks, tablets, cameras, game consoles, iPods and other MP3 players, navigation devices, and GPS devices. Such devices typically have a display screen and a housing. The cut film pieces of the protective adhesive film may be applied to the screen and/or other portions of the digital device (such as an edge, side, corner or other portion of the housing, and/or the bezel) to protect it from damage, using methods described in this document. In some embodiments, the film may be applied to corners, edges and/or sides of the device to provide a shock-absorbing, impact-resistant skin for the device. The cut film pieces may be designed such that they contain openings to correspond to various device components and thus do not block input or output ports, connections, jacks, or entry points for access to internal components of the device. The cut film may be flexible, to permit its application onto curved surfaces smoothly without the appearance of gaps, wrinkles, or air bubbles.

In some embodiments, the protective adhesive film includes a cap sheet (e.g., a casting film and/or a casting sheet). The cap sheet may be disposed on a second major surface of the protective film. The cap sheet may be formed out of a material(s) that is sufficiently rigid that the pressure applied by a mechanical smoothing device (e.g., a squeegee) does not cause the cap sheet or the protective film to deform (e.g., “orange peel”). Further, the cap sheet may withstand an increased pressure from the mechanical smoothing device, which may result in reduced air bubbles between the protective film and an electronic device. Additionally, the cap sheet may protect the second major surface of the protective film during manufacture, transport, and/or the end-user installation processes. This may provide an advantage over secondary application/release tapes that include a cured liquid for top coating (e.g., a polyurethane and/or an acrylic material). The secondary application/release tapes include an adhesive that may roughen or distort the second major surface of the pressure adhesive layer, which may reduce the optical clarity of the protective film.

The cap sheet may be formed out of polyester. A polyester cap sheet (e.g., a laminating roll) that is about 2 mils thick may have sufficient rigidity and flexibility to prevent the cap sheet and/or the protective film from deforming. Additionally, polyester may withstand the extrusion temperature of the protective film (e.g., about 320-350′ F.). The cap sheet may comprise polyester, polypropylene, nylon, polyimide, and similar high-temperature resistant (e.g., able to resist the temperature of the protective film extrusion, such as about 320-350° F.) and/or high melt point films e.g., a melt point greater than the temperature of the protective film extrusion, such as about 320-350° F.). The cap sheet may be from about 0.92 mils (i.e., about 24 microns) to about 10 mils thick (i.e., about 254 microns). In some embodiments, the cap sheet may be about 2 mils (i.e., about 24 microns) thick. The cap sheet may be embossed, brushed, or flat. In some embodiments, a micro-mane surface structure is defined in a cap sheet.

Suitable materials for the cap sheet and protective film may include one or more of the following materials (or similar materials) manufactured by Argotec. Inc. of Greenfield, Mass. (or other polyurethane manufacturing companies): ARGOTHANE® aromatic polyethers/thermoplastic polyurethane (part numbers 17103, 17200, 18103, 18212, 18214, 18215, 18233, 18235, 18242, 18247, 18248, 18305, 18411, 18422, 18433, 18450-FR, 18452-FR), ARGOTHANE® aromatic polyesters/thermoplastic polyurethane (part numbers 19102, 19103, 19205, 19422, 19424, 19426, D7101, 27303, 27370, 28304, 29100, 29102, 29213, 29222, 29285, and/or 29300), ARGOTHANE® aliphatic polyesters (part numbers 3751 and/or AGKR), ARGOTHANE® aliphatic polycaprolactones/thermoplastic polyurethane (part number 46510) ARGOTHANE® waterproof breathable films/thermoplastic polyurethane (part numbers TX1540 and/or TX2060), ARGOFLEX® waterproof-breathable films/thermoplastic polyurethane (part numbers TX 1300, TX 1500, and/or TX2000), and/or ARGOTEC® film no. 49522.

In some embodiments, at least a portion of a surface of the cap sheet (e.g., a casting film and/or a casting sheet) has a texture (e.g., brushed, ribs, ridges, grooves, raised dots, etc). The textured surface of the cap sheet may be disposed on the second major surface of the protective film. The textured surface may cause micro air pockets to form between the textured surface and the second major surface of the protective film. The micro air pockets are small air pockets that form in gaps between the textured surface and the second major surface of the protective film. The micro air pockets may allow the cap sheet to be more easily removed from the pressure-sensitive adhesive layer (e.g., by reducing a seal caused by two substantially smooth surfaces). In the alternative, the second major surface of the protective film may include a textured surface. However, this may decrease the optical clarity of the protective film and, therefore, may be less desirable to the end user. In some embodiments, the cap sheet has a texture that defines a micro-matte surface on the second major surface of the protective film.

A mechanical smoothing device may be used to apply a pressure to an exposed surface of the cap sheet. The cap sheet may allow for the use of a wider and/or more rigid mechanical smoothing device during the installation process as a result of the rigidity of the cap sheet. For example, the mechanical smoothing device may have approximately the same width as the entire electronic device (e.g., eReader, computer notebook, tablet, etc.) or a portion of the electronic device (such as a display screen) to which the protective adhesive layer is to be applied. Additionally, the cap sheet may be sufficiently rigid to withstand the pressure applied by the mechanical smoothing device to minimize resulting damage (e.g., distortion) to the protective adhesive film. The smoothing device may be formed from a variety of materials, including a thick, heavy gauge paper (e.g., greater than about 50 mils thick, between about 50-150 mils thick, between about 50-90 mils thick, between about 50-80 mils thick, between about 60-80 mils thick, or about 70 mils thick), polyvinyl chloride acetate (PVCA), unplasticized polyvinyl chloride (uPVC), silicone rubber, ethylene propylene diene monomer (M-class) rubber (EPDM rubber), and/or other semi-rigid rubbers, and/or rigid plastics, such as rigid polyethylene (e.g., HDPE, MDPE, or LDPE), polyvinyl chloride (PVC), and/or polypropylene. For example, the smoothing device may be formed from silicone rubber and/or EPDM rubber that is about 60 to 90 Shore A durometer in hardness.

A wider mechanical smoothing device may provide several advantages. For example, a wider mechanical smoothing device only needs to be applied once (as it may be about the same width as a screen of an eReader, etc.), thereby decreasing installation time. Additionally, a wider mechanical smoothing device may minimize unintended skewing, repositioning and/or stretching of the protective adhesive film that may occur as a result of multiple squeegee applications (e.g., in different directions with respect to the screen of an eReader, etc.). A wider and harder mechanical smoothing device allows the user to apply an increased downward force/pressure on the cap sheet, resulting in an increased adherence of the protective adhesive film to the electronic device and/or reduced air bubbles between the protective adhesive film and the electronic device.

In some embodiments, the protective film includes a body and at least one tab that extends outwardly from the body. In some embodiments, the protective film includes two tabs, for example, on opposing sides of the protective film. The tabs may be positioned in the middle of each opposing side, or in any other position along the edge of the protective film. The tabs may function as grab handles to allow a user to more accurately position the protective adhesive film and cap sheet on the electronic device and/or to reduce fingerprints on the protective adhesive film. In some embodiments, the tabs include perforations, allowing the user to more easily remove the tabs after installation.

FIG. 1 illustrates an exemplary first step for applying an adhesive film (e.g., a protective adhesive film and/or a micro-matte protective film) to an electronic device. In this step, a portion of a backing layer 20 is removed from an adhesive film 10 to expose an adhesive area 30. The adhesive area 30 is disposed on at least a portion of a first major surface 40 of the protective adhesive film 10. Prior to removing the backing layer 20, the adhesive film 10 may be modified by cutting (e.g., by die cutting, plotter cutting, or other methods) to create segments matched in size and shape to chosen surface areas on a particular device to be protected. Alternatively, the adhesive film 10 may be pre-cut to match a desired area on an electronic device.

Referring to FIG. 2, after the backing layer 20 is partially or fully removed, the adhesive area 30 may be positioned to contact and align with an exposed surface portion 50 of an electronic device 60 (e.g., a display surface). In some embodiments, the exposed surface portion 50 may be a small, large, or an entire portion of an exposed surface 70 of the electronic device 60. In some embodiments, the adhesive film 10 and/or the adhesive area 30 are aligned to the electronic device 60 (e.g., aligned to the surface portion 50, e.g., an edge of the exposed surface 70). For example, openings 75 in the adhesive film 10 may be aligned to corresponding components 65 (e.g., input and/or output ports, buttons, etc.) of the electronic device 60. In some embodiments, prior to contacting the adhesive film 10 to the electronic device 60, at least a portion of the exposed surface 70 of the electronic device may be cleaned, for example, by rubbing or polishing the at least a portion of exposed surface 70 with a dry tissue or towelette.

The film 10 (e.g., a protective adhesive film and/or a micro-matte protective film) may be applied to the electronic device 60 “as is.” There is no need to apply any liquid or other additive to any portion of the exposed surface 70 or the adhesive area 30 at any time during the process.

As illustrated in FIG. 3, after the film 10 is aligned to the device 60, the backing layer 20 is completely removed from the first major surface 40 of the film 10, and the remaining adhesive area 30 of the film 10 is aligned to contact the device 60.

Referring to FIG. 4, a mechanical smoothing device 100 (e.g., a squeegee, a device having a resilient edge, or a hand) may be used to apply a pressure to the second major surface 90 of the film 10. The pressure may cause the adhesive area 30 to press against the exposed surface portion 50 of the electronic device 20. In some embodiments, the mechanical smoothing device 100 applies the pressure from a central area 105 to an edge 110 of the second major surface 90 continuing in different radial directions from the central area 105 across the second major surface 90. In some embodiments, the mechanical smoothing device 100 applies the pressure starting at or near a trapped air pocket or an air bubble and continues to an edge 110. Any haze or remaining trapped air bubbles, if less than about 2-3 mm in diameter, may be left to diffuse out through the protective adhesive film 10 (e.g., an air-permeable film), generally disappearing within 24 hours.

In some embodiments, the method may include repositioning the film 10 (e.g., a protective adhesive film and/or micro-matte protective film) after it has been adhered to the exposed surface portion 50 of the device 20. For example, the method may include lifting a portion of the film 10 away from the exposed surface portion 50 of the device 20 and reapplying (e.g., re-contacting) the portion to the exposed surface portion 50 of the device 20, which may be helpful in repositioning and/or re-aligning the film 10 and/or in removing air bubbles. In some embodiments, additional mechanical smoothing (e.g., by hand or with a mechanical device) may be used to ensure that the film 10 is adhered to the edges 110 of the device 20.

FIGS. 5-8 illustrate an alternative procedure that may be used for larger electronic devices, such as tablets, notebooks, and notebooks. In this embodiment, the protective adhesive film includes a cap sheet layer (e.g., a casting film and/or a casting sheet). Referring to FIG. 5, a portion of a backing layer 420 is removed from an adhesive film 410 to expose an adhesive area 430. In some embodiments, the adhesive film 410 is a micro-matte protective adhesive film. The adhesive area 430 is disposed on at least a portion of a first major surface 440 of the protective adhesive film 410. A cap sheet 510 is disposed on a second major surface of the protective adhesive film 410. Prior to removing the backing layer 420, the film 410, together with the cap sheet 510 as one piece or separately from the cap sheet 510, may be shaped by cutting (e.g., by die cutting, plotter cutting, or other methods) to create segments, with a cap sheet 510 layered on the adhesive film 410, matched in size and shape to chosen surface areas on a particular device to be protected. Alternatively, the protective adhesive film 410 and cap sheet 510 may be pre-cut to match a desired area on an electronic device.

After the adhesive is exposed, FIG. 6 illustrates that the adhesive area 430 may be contacted to an exposed surface portion 450 of an electronic device 460 (e.g., a display surface). In some embodiments, the exposed surface portion 450 may be any portion of exposed surface 470 including the entire exposed surface 470. In some embodiments, the adhesive film 410 and/or the adhesive area 430 may be positioned to contact and align with an exposed surface portion 450 of the electronic device 460. For example, openings 475 in the adhesive film 410 may be aligned to corresponding components 465 (e.g., input and/or output ports, buttons, etc.) of the electronic device 460. In some embodiments, at least one optional tab 415 extends from the adhesive film 410. A user may hold the at least one optional tab 415 while positioning, contacting, and/or aligning the adhesive area 430 to the exposed surface portion 450 of the electronic device 460. In some embodiments, prior to contacting the adhesive film 410 to the electronic device 460, at least a portion of exposed surface 470 of the electronic device may be cleaned, for example, by rubbing or polishing the at least a portion of exposed surface 470 with a dry tissue or towelette. In some embodiments, no liquid or other additive is applied to the adhesive film 410, the adhesive area 430, and/or the electronic device 460.

Referring to FIG. 7, a mechanical smoothing device 500 (e.g., a squeegee, oversized squeegee, a device having a resilient edge, or a hand) may be used to apply a pressure to the cap sheet 510 disposed on a second major surface 490 of the film 410. The pressure may causes the adhesive area 430 to press against the exposed surface portion 450 of the electronic device 460 (as depicted in FIG. 6). The mechanical smoothing device 500 may be applied starting at an edge 515 of the electronic device 420 and proceeding across the width 520 of the electronic device 420. An optional second mechanical smoothing step may be applied in the opposite direction of the first mechanical smoothing step. After pressure is applied with the mechanical smoothing device 500, the cap sheet 510 is removed (e.g., peeled off) to expose the second major surface 490 of the film 410, as illustrated in FIG. 8. Any haze or remaining trapped air bubbles, if less than about 2-3 mm in diameter, may be left to diffuse out through the protective adhesive film 410 (e.g., an air-permeable film), generally disappearing within 24 hours. For example, air bubbles may diffuse into the first major surface 440 of the film 410 and out the second major surface 490 of the film 410. In some embodiments, after the mechanical smoothing step, the optional hold tabs 415 may be removed from the film 410 by pulling along optional perforations (not shown) or by cutting off the hold tabs 415.

The method improves the adherence of the film to the surface of the device, and provides a higher quality (e.g., less damaged, more transparent, and/or more accurately placed) protective film. The method further reduces the number of remaining trapped air bubbles. The method further reduces the installation time of applying a protective film to an electronic device. 

What is claimed is:
 1. A protective film product for use on a touchscreen of a mobile telephone, the protective film product comprising: a protective film having a proximal end, a distal end and two opposing sides, the proximal end, distal end and two opposing sides together forming a perimeter of the protective film, the perimeter surrounding a planar portion of the protective film that includes a first major surface and a second major surface opposite the first major surface, the first major surface separated from the second major surface by a thickness, the protective film having a structure configured to preserve touch sensitivity and clarity of the touchscreen of the mobile telephone; one or more adhesive layers disposed on the first major surface of the protective film, the one or more adhesive layers having planar dimensions substantially coextensive with first major surface of the protective film, the one or more adhesive layers including one or more components having molecular weights sufficiently low to cause at least a portion of the one or more components to migrate into the protective film to modify characteristics of the protective film; a removable backing layer having a planar surface in contact with an outermost adhesive layer of the one or more adhesive layers, the backing layer preventing contact of the one or more adhesive layers by other objects prior to installation of the protective film onto a surface portion of the mobile telephone, the backing layer having planar dimensions substantially coextensive with the first major surface of the protective film; and a removable cap sheet disposed on the second major surface of the protective film, wherein the removable cap sheet is not applied to the protective film as a liquid top coating and comprises a film applied to the second major surface of the protective film such that micro air pockets are formed in gaps between a surface of the cap sheet and the second major surface of the protective film wherein the protective film comprises a urethane sheet and wherein at least one of the one or more adhesive layers consists essentially of a copolymer of an acrylate polymer and silicone macromer side chains.
 2. The protective film product according to claim 1, further including at least one opening formed in the protective film for alignment with and access to a respective one or more of an input port, an output port, a connection, a jack, and a button of the mobile telephone.
 3. The protective film product according to claim 1, wherein a micro-matte surface structure is formed as at least part of the second major surface of the protective film.
 4. The protective film product according to claim 1, further including a micro-matte layer coating on the second major surface of the protective film.
 5. The protective film product according to claim 1, wherein the adhesive layer has a thickness between about 10 microns and about 100 microns.
 6. The protective film product according to claim 1, wherein the one or more adhesive layers comprise an adhesive that provides tack sufficient to securely adhere the protective film to a surface portion of the mobile telephone without addition of a liquid during installation of the protective film.
 7. The protective film product according to claim 1, further comprising a first tab extending outward at a first edge of the protective film product and a second tab extending outward at a second edge of the protective film product, wherein the first edge is opposite the second edge, the first tab and the second tab each being sized to form a grab handle to allow a user to position the first major surface of the protective film during installation of the protective film onto the surface portion of the mobile telephone.
 8. The protective film product according to claim 7, further comprising first and second sets of perforations, the first set of perforations removably dividing the first tab from at least one of the protective film and the removable cap sheet, and the second set of perforations removably dividing the second tab from at least one of the protective film and the removable cap sheet, the first set of perforations allowing removal of the first tab after positioning and installation of the protective film onto the surface portion of the portable electronic device, and the second set of perforations allowing removal of the second tab after positioning and installation of the protective film onto the surface portion of the mobile telephone.
 9. The protective film product according to claim 1, wherein when the low molecular weight components migrate into the protective film and modify the characteristics of the protective film, the protective film becomes more impact resistant.
 10. The protective film product according to claim 1, wherein the low molecular weight components migrate into the protective film and modify the characteristics of the protective film to make the protective film more flexible.
 11. The protective film product according to claim 1, wherein the low molecular weight components comprise a tackifier.
 12. The protective film product according to claim 1, wherein at least one of the one or more adhesive layers comprises silicone.
 13. The protective film product according to claim 1, wherein at least one of the one or more adhesive layers includes a self-healing adhesive.
 14. The protective film product according to claim 1, wherein the thickness of protective film is between about 75 microns and about 400 microns.
 15. The protective film product according to claim 1, wherein the thickness of the protective film at a first portion of the protective film is different from the thickness at a second portion of the protective film, wherein the first portion and the second portion of the protective film correspond to different portions of the mobile telephone.
 16. The protective film product according to claim 1, wherein the protective film comprises a polyurethane sheet.
 17. A protective film product for protecting at least a portion of a mobile telephone, the protective film product comprising: a protective film having a first major surface and a second major surface opposite the first major surface, the first major surface and the second major surface being defined by a perimeter, the protective film being air permeable to permit diffusion of gases; an adhesive layer disposed on the first major surface of the protective film; a removable backing layer in contact with the adhesive layer to bar contact with the adhesive layer prior to removal of the backing layer during installation of the protective film onto a surface portion of the mobile telephone; and a removable cap sheet disposed on the second major surface of the protective film, wherein the removable cap sheet comprises a film sheet that is more rigid than the protective film and is applied to the second major surface of the protective film such that micro air pockets are formed in gaps between a surface of the cap sheet and the second major surface of the protective film.
 18. The protective film product according to claim 17, further comprising: a first tab extending outward at a first edge of the protective film; a second tab extending outward near a second edge of the protective film opposite the first edge; a first set of perforations and a second set of perforations, the first set of perforations removably dividing the first tab from at least one of the protective film and the removable cap sheet, and the second set of perforations removably dividing the second tab from at least one of the protective film and the removable cap sheet, wherein the first tab and the second tab are each sized to form a grab handle to allow a user to position the first major surface of the protective film during installation of the protective film onto a surface portion of the mobile telephone, the first tab and the second tab being removable from the protective film product at, respectively, the first and second sets of perforations, and the first set of perforations allows removal of the first, and the second set of perforations allowing removal of the second tab.
 19. The protective film product according to claim 17, wherein the adhesive layer includes low molecular weight components, the low molecular weight components having characteristics permitting the low molecular weight components to migrate into the protective film and modify characteristics of the protective film.
 20. The protective film product according to claim 19, wherein the characteristics of the protective film that are modified by migration of the low molecular weight components include impact resistance and flexibility.
 21. The protective film product according to claim 19, wherein the low molecular weight components comprise a tackifier.
 22. The protective film product according to claim 17, wherein the adhesive layer comprises a dry pressure sensitive adhesive.
 23. A protective film product for use with a portable electronic device, the protective film product comprising: a protective film having a first major surface and a second major surface opposite the first major surface; an adhesive layer disposed on the first major surface of the protective film, the adhesive layer comprising an adhesive that provides tack sufficient to securely adhere the protective film to a surface portion of the portable electronic device without the necessity of a liquid during installation of the protective film and further allows one or more of positioning and repositioning during the installation, wherein the adhesive layer includes low molecular weight components, the low molecular weight components adapted to migrate into the protective film and modify the characteristics of the protective film; a removable backing layer disposed over the adhesive layer to protect the adhesive layer from contact by other objects prior to removal of the removable backing layer during installation of the protective film onto a surface of the portable electronic device; and a removable cap sheet formed from a rigid material and disposed on the second major surface of the protective film, wherein micro air pockets are formed in gaps between a surface of the cap sheet and the second major surface of the protective film wherein the protective film comprises a urethane sheet and wherein at least one of the one or more adhesive layers consists essentially of a copolymer of an acrylate polymer and silicone macromer side chains.
 24. The protective film product according to claim 23, further comprising: a first tab and a second tab each extending from respective edges of the protective film product removable by tearing the first tab at a first set of perforations and tearing the second tab at a second sets of perforations, wherein the first set of perforations removably divides the first tab from at least one of the protective film and the cap sheet, and the second set of perforations removably divides the second tab from at least one of the protective film and the removable cap sheet, the first set of perforations allowing removal of the first tab after positioning and installation of the protective film onto the surface portion of the portable electronic device, and the second set of perforations allowing removal of the second tab after positioning and installation of the protective film onto the surface portion of the portable electronic device.
 25. The protective film product according to claim 23, wherein the characteristics of the protective film product that are modified by migration of the low molecular weight components into the protective film include at least one of improved impact resistance and increased flexibility.
 26. A protective film product for a portable electronic device, the protective film product comprising: a protective film having a first major surface and a second major surface opposite the first major surface, wherein the protective film includes a first region corresponding to a first portion of the portable electronic device and a second region corresponding to a second portion of the portable electronic device, and wherein the first and second regions of the protective film have different thicknesses; an adhesive layer disposed on the first major surface of the protective film; and a removable cap sheet disposed on the second major surface of the protective film, wherein micro air pockets are formed in gaps between a surface of the cap sheet and the second major surface of the protective film. 